Acetylene
(C2H2) is not an air gas, but a synthesis gas generally
produced from the reaction of calcium carbide with water. It was burnt
in "acetylene lamps" to light homes and mining tunnels in the 19th
century. A gaseous hydrocarbon, it is colorless, has a strong garlic
odor, is unstable, highly combustible, and produces a very hot flame
(over 3000°C or 5400°F) when combined with oxygen.
Laboratories & analysis
Acetylene is the fuel gas in atomic absorption spectrophotometry (AAS)
Welding,
Cutting & Coating
- Acetylene is the most effective and versatile fuel gas; C2H2 enabling manual applications such as welding, brazing, cutting, straightening or any other localised heating process.
Argon
The atmosphere contains about 0.9 % of argon. A neutral and colorless
gas like nitrogen, it does not however exist in nature other than in
the air. It cannot sustain life, but it is highly used in certain
industrial applications due to its high level of chemical inertness and
the relative ease with which it can be produced.
Argon
Physical Properties
- Argon is a monatomic, colorless, odorless, tasteless and nontoxic gas.
Used pure and in mixtures for industrial and hospital analyses and quality control. More particularly, argon is used as plasma gas in inductive coupled plasma emission spectrometry (ICP), blanket gas in graphite funace atomic absorption spectrometry (GFAAS) and as carrier gas in gas chromatography for various detector. In mixture with methane, argon is used in Geiger counter and in the detector of X Ray Fluorescence (XRF) as quentching gas.
Welding,
Cutting & Coating
Argon is a shield gas used in arc welding, root shielding and plasma
cutting. Argon protects welds against oxidation as well as reduces fume
emissions during welding.
Electronics
Ultra-pure argon is used as carrier gas for reactive molecules, as
inert gas to protect semiconductors against impurities (e.g. Argon
provides the atmosphere for growing crystals of silicon and germanium).
Under ionic state, argon is used for sputtering, ion implantation,
annealing and etching processes in semiconductor or high performance
material manufacturing.
Carbon Dioxide
Carbon dioxide gas is formed from the combination of two elements:
carbon and oxygen. It is produced from the combustion of coal or
hydrocarbons, the fermentation of liquids and the breathing of humans
and animals. Found in small proportions in the atmosphere, it is
assimilated by plants which in turn produce oxygen. CO2 gas has a
slightly irritating odor, is colorless and heavier than air. It cannot
sustain life. It freezes at -78.5 °C to form carbon dioxide
snow. In an aqueous solution it forms carbonic acid, which is too
unstable to be easily isolated.
Humans use carbon dioxide in many different ways. The most familiar
example is its use in soft drinks and beer, to make them fizzy. Carbon
dioxide released by baking powder or yeast makes cake batter rise.
Some fire extinguishers use carbon dioxide because it is denser than
air. Carbon dioxide can blanket a fire, because of its heaviness. It
prevents oxygen from getting to the fire and as a result, the burning
material is deprived of the oxygen it needs to continue burning.
Carbon dioxide is also used in a technology called supercritical fluid
extraction that is used to decaffeinate coffee. The solid form of
carbon dioxide, commonly known as Dry Ice, is used in theatres to
create stage fogs and make things like "magic potions" bubble.
HELIUM
Helium is abundant in the Sun's atmosphere and is found at trace level
in the Earth's atmosphere. The name helium comes from the Greek
ἥλιος (helios) meaning "the
Sun". However, it may also be found in fossil form in natural gas
pockets in some oil fields, where it is extracted by drilling deep into
the subsoil of certain regions in the U.S.A., Algeria and Poland.
Helium is an extremely light gas (its density is 0.169 kg/m3) and is
therefore very volatile. It is colorless, odorless, non-flammable and
completely inert. It cannot sustain life.
Helium is the most commonly gas used as carrier in gas chromatography.
Under liquid state, at -269 °C, helium is the cooling fluid for
the MRI, NMR or EPR magnets.
Other industries
- Balloon inflation
- leak detection
- because the boiling point of helium is close (-269 °C or -452 °F) to the absolute zero (-273 °C) He is used for cooling of superconducting magnets
- used in helium neon lasers, helium is a component of the special mixtures used in CO2 lasers (§ LASAL™).
- blanket gas to exclude air from certain fabrication processes.
- helium is used as a heat
transfer material.
Molecular Weight - Molecular weight : 4.0026
g/mol
Solid phase - Melting point (under 26 atm)
: -272.2 °C
Liquid phase - Liquid density (1.013 bar at boiling point) : 124.96 kg/m3
- Liquid/gas equivalent (1.013 bar and 15 °C (59 °F)) : 748 vol/vol
- Boiling point (1.013 bar) : -269 °C
- Latent heat of vaporization (1.013 bar at boiling point) : 20.3 kJ/kg
Critical point
- Critical temperature : -268 °C
- Critical pressure : 2.275 bar
- Critical density : 69.64 kg/m3
Hydrogen
H2: THE GREEN GAS Discovered by Henry Cavendish in 1766, hydrogen owes
it name to Lavoisier, who combined the Greek hydor, water, and genen,
to engender. It is the lightest gas in the world and therefore is not
held by the earth’s gravity.
Hydrogen is only found in the atmosphere at trace levels ; it is
synthesized from hydrocarbons (petroleum and petroleum by-products) and
from water where it constitutes the lightest fraction of the H2O
molecule. Hydrogen gas is colorless, highly flammable, very light,
cannot sustain life and reacts easily with other chemical substances.
The
fuel cell
The world dreams about driving in a silent car that doesn’t
pollute! Hydrogen is a clean energy carrier. Used in a fuel cell, it
combines with oxygen to efficiently produce electricity and
doesn’t emit anything… except water.
A REACTANT PRIZED BY THE CHEMICAL INDUSTRIES; AN EXCELLENT CLEAN ENERGY
CARRIER
Food
and Beverage
Pure hydrogen is used for the production of plastics, polyester and
nylon. H2 gas is also used in the hydrogenation of amines and fatty
acids (food oils).
- Glass, Cement and Lime
Hydrogen is an active gas used in combination with nitrogen to create a reductive atmosphere over the tin bath in the FLOAT glass process. Hydrogen is used for heat treatment (oxy-hydrogen flame) of the hollow glass and the optic fibers pre-forms. - Metals industry
Reductive atmosphere for various processes of heat treatment. - Laboratories &
analysis
Hydrogen is used as a carrier gas in gas chromatography and in various analytical instrument applications, most commonly as a fuel component of combustion gases for Flame Ionization (FID) and Flame Photometric (FPD) detectors. Spark discharge analyzers, total hydrocarbons measurements use also hydrogen mixtures. - Welding, Cutting & Coating Heat treatment of various metals
- Oil and Gas Desulurization of fuel-oil and gasoline
- Electronics
Hydrogen is used as carrier gas in semiconductor processes, especially for silicon deposition or crystal growing and as a scavenger gas in atmosphere soldering as well as for annealing copper films. The use of forming gases (that is H2 diluted in nitrogen) allows virtually a complete elimination of oxygen and its inconveniences in medium to high temperature processes.
NITROGEN
Nitrogen is mainly found in the atmosphere, where it accounts for 78 %
by volume of the air we breath. But nitrogen is also found: - in the
Earth's crust, to a limited extent (in the form of nitrates, etc.), -
in organic form (in the living or dead plants and organisms which form
humus) - and in mineral form (ammonia), and thus contributes to soil
fertility. In gaseous form, nitrogen is a neutral and colorless gas. It
is inserting and does not sustain life.
Chemicals
Nitrogen can be used for blanketing, as well as for :
- Storage for protecting raw materials or finished products in liquid form from the formation of peroxides and/or gum, and from contamination by oxygenated components
- Regeneration of purification beds (alumina and molecular sieve)
- Preparation of catalysts and transportion of polymer powders
- Medium for the exhaust of emitted heat in fluid bed reactors
- Temperature Control in reactors.
Pharmaceuticals
Nitrogen is used for inerting, cryo-grinding, lyophilisation, drying,
liquid phase transfer of products or synthesis intermediates;
cryo-condensation of waste gases and low temperature storage.
Food
and Beverage
Liquid nitrogen: N2 is the most used cryogenic fluid, to chill, freeze
or store food products. Gaseous nitrogen: N2 is very commonly used in
contact with foodstuffs to avoid oxidation or micro-organism growth by
inerting of liquids. Modified Atmosphere Packaging (MAP) preserves and
protects foods ( pure nitrogen or mixed with CO2)
(§ALIGAL™). Glass, Cement and Lime Nitrogen
is used as an inert gas especially to create, in combination with
hydrogen, a reductive atmosphere over the tin bath in the float glass
process.
Healthcare
Low-temperature preservation of living tissues and cells
Laboratories
& analysis
Nitrogen is used as a carrier gas in gas chromatography for various
industrial and hospital analyses and quality control. Nitrogen is the
balance gas of the calibration gas mixtures for environmental
monitoring systems and industrial hygiene gas mixtures. Nitrogen is
largely used as purge, dryier or blanket gas for analyzers or chemical
reactors (under gaseous state or at low temperature liquid state).
Welding, Cutting & Coating Heat treatment of various metals.
Nitrogen is a component of the special mixtures used in CO2 lasers
(§ LASAL™).
Oil
and Gas Quality
Protection of products and facilities (blanketing)
Electronics
Nitrogen is used as carrier gas for overall protection against
impurities and oxidation in semiconductor and soldering processes. In
its cold and liquid form, N2 is used as a cooling medium in the
environmental testing of electronic devices.
Automotive
& transportation
Gas Assisted Injection Moul style="font-size:12px;"ding requires pressures between 10 bar (145
psi) and 200 bar (2900 psi) and a nitrogen content of between 98.0 %
and 99.9 %. Tires filling with nitrogen increases their lifetime and
therefore decreases the recycling or treatment of this waste.
Other
industries
Pneumatic transportation of
powdered flammable materials (charcoal). English Units Normal Boiling
Point (1 atm) Gas Phase Properties @ 32°F & @1 atm
Liquid Phase
For example, oxygen makes up by weight: - 46% of the Earth's crust (in
the form of oxides, silicates, etc.) - 89% of the Earth's water (in the
form of molecule - 21% of the air we breathe - 62% of the human body
(in the form of molecules) In its most well-known form (it constitutes
21% of the atmosphere), it is a tasteless, odorless and colorless gas
essential to life. IT CAN COMBINE WITH ALL THE OTHER ELEMENTS EXCEPT
THE RARE GASES IN ORDER TO OXIDIZE THEM AND CONSEQUENTLY PRODUCE
ENERGY. Oxygen can be used pure in chemical oxidation reactions such as
the production of ethylene oxide (EO), propylene oxide (PO), ethylene
dichloride (EDC), vinyl acetate monomer (VAM), titanium dioxide (TiO2),
ferric sulfate and also for the debottlenecking of air-based processes
such as those in the production of acrylonitrile and purified
terephtalic acid (PTA). O2 is also used in the production of synthesis
gas (H2/CO).
Pharmaceuticals
Oxygen is used in chemical synthesis, for enrichment of air during
fermentation, for treatment of wastewater and flame sealing of glass
ampul style="font-size:12px;"s for finished products.
Food
and Beverage
Oxygenation of fish-breeding tanks Glass, Cement and Lime
Mainly used for the glass melting and generally for all oxy-combustion
process.
Healthcare
Treatment of respiratory insufficiencies and resuscitation, in
hyperbaric oxygen changes for treatment of carbon monoxide poisoning.
Metals
industry
As in the iron and steel industry (Decarburization of hot metal to
produce steel, and to enrich blast furnace air), oxygen is used in non
ferrous primary production, secondary smelting etc.
Laboratories
& analysis
Oxygen is used in calibration gas mixtures for petrochemical industry;
environmental emission monitoring, industrial hygiene or safety
monitors and trace impurity analyzers. Oxygen is used in bomb
calorimeters to measure the PCI of hydrocarbons or coal and in
oxidation reactions.
Welding,
Cutting & Coating
With acetylen or LPG's, oxygen allows to boost the flame properties in
flame torches and burners (flame temperature, specific flame output
power). The second way in which oxygen is used is to provide an highly
effective jet for oxy-cutting carbon steels (non- and low-alloyed).
Oil
and Gas
Oxygen is used in raffinery to enrich air of regeneration of Fluid
Cracking Catalytic units (FCC) (up to 28 % in O2).
OXYGEN
O2 THE REACTIVE GAS:
The oxygen element was discovered in 1774 by Joseph Priestley. It was only later that its high level of chemical reactivity was discovered. Lavoisier renamed 'vital air' to oxygène in 1777 from the Greek -ὀξύς (oxys) (acid) and -γενής (-genes) (producer, literally begetter).
It is the most abundant element on the earth’s surface.
For example, oxygen makes up by weight:
- 46% of the Earth's crust (in the form of oxides, silicates, etc.)
- 89% of the Earth's water (in the form of molecules)
- 21% of the air we breathe
- 62% of the human body (in the form of molecules)
In its most well-known form (it constitutes 21% of the atmosphere), it is a tasteless, odorless and colorless gas essential to life. IT CAN COMBINE WITH ALL THE OTHER ELEMENTS EXCEPT THE RARE GASES IN ORDER TO OXIDIZE THEM AND CONSEQUENTLY PRODUCE ENERGY.
Main applications
- Industries Applications
- Chemicals
Oxygen is used to improve the yield of a large number of petrochemical processes. Oxygen can be used pure in chemical oxidation reactions such as the production of ethylene oxide (EO), propylene oxide (PO), ethylene dichloride (EDC), vinyl acetate monomer (VAM), titanium dioxide (TiO2), ferric sulfate and also for the debottlenecking of air-based processes such as those in the production of acrylonitrile and purified terephtalic acid (PTA). O2 is also used in the production of synthesis gas (H2/CO). - Pharmaceuticals
Oxygen is used in chemical synthesis, for enrichment of air during fermentation, for treatment of wastewater and flame sealing of glass ampuls for finished products. - Food and Beverage
Oxygenation of fish-breeding tanks - Glass, Cement and Lime
Mainly used for the glass melting and generally for all oxy-combustion process. - Healthcare
Treatment of respiratory insufficiencies and resuscitation, in hyperbaric oxygen changes for treatment of carbon monoxide poisoning. - Metals industry
As in the iron and steel industry (Decarburization of hot metal to produce steel, and to enrich blast furnace air), oxygen is used in non ferrous primary production, secondary smelting etc. - Laboratories &
analysis
Oxygen is used in calibration gas mixtures for petrochemical industry; environmental emission monitoring, industrial hygiene or safety monitors and trace impurity analyzers. Oxygen is used in bomb calorimeters to measure the PCI of hydrocarbons or coal and in oxidation reactions. - Welding, Cutting &
Coating
With acetylen or LPG's, oxygen allows to boost the flame properties in flame torches and burners (flame temperature, specific flame output power). The second way in which oxygen is used is to provide an highly effective jet for oxy-cutting carbon steels (non- and low-alloyed). - Oil and Gas
Oxygen is used in raffinery to enrich air of regeneration of Fluid Cracking Catalytic units (FCC) (up to 28 % in O2). - Pulp and paper
Environment-friendly paper pulp bleaching : Oxygen is mainly used in the delignification step, O2 participates in the boosting of bleaching operations like alkaline extraction (Eo), in white or black liquors oxidation, polysulfure liquors production as well as combustion (lime burning kiln, boilers boosting). Oxygen is also used in the waste treatment and as precursor of ozone. - Electronics
Ultra-pure oxygen is used to oxidize certain materials, such as Si to SiO2, or ashing of photoresists and to achieve chemical vapor deposition of oxides. It is also used to make ozone for oxidations or cleaning. - Space and Aeronautics
Oxygen is used in their liquid states as ergols for the propulsion of the cryogenic stages of the Ariane rockets. - Environment
In a biological basin, oxygen enhances the waste water treatment (BOD, sludges, odors, energy). Oxygen also improves waste treatment, decreasing the amount of incineration emissions by a factor of up to 7. - Other industries
Biological water purification, clean waste incineration, ozone synthesis